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Its properties are thus similar to those of fluorine, chlorine, and iodine, and tend to be intermediate between those of chlorine and iodine, the two neighbouring halogens. Bromine has the electron configuration [Ar]4s 2 3d 10 4p 5, with the seven electrons in the fourth and outermost shell acting as its valence electrons.
Bromine addition to alkene reaction mechanism. An old qualitative test for the presence of the alkene functional group is that alkenes turn brown aqueous bromine solutions colourless, forming a bromohydrin with some of the dibromoalkane also produced. The reaction passes through a short-lived strongly electrophilic bromonium intermediate.
Bromine water, Br 2. Bromine water is an oxidizing, intense brown mixture containing diatomic bromine (Br 2) dissolved in water (H 2 O). [1] It is often used as a reactive in chemical assays of recognition for substances which react with bromine in an aqueous environment with the halogenation mechanism, mainly unsaturated carbon compounds (carbon compounds with 1 or more double or triple bond(s)).
Tribromine octoxide is a binary inorganic compound of bromine and oxygen with the chemical formula Br 3 O 8. [ 1 ] [ 2 ] This is a free radical and one of the most complex bromine oxides . Synthesis
Free-radical substitution with bromine is commonly used to prepare organobromine compounds. Carbonyl-containing, benzylic, allylic substrates are especially prone to this reactions. For example, the commercially significant bromoacetic acid is generated directly from acetic acid and bromine in the presence of phosphorus tribromide catalyst:
Bromine monochloride, also called bromine(I) chloride, bromochloride, and bromine chloride, is an interhalogen inorganic compound with chemical formula BrCl. It is a very reactive golden yellow gas with boiling point 5 °C and melting point −66 °C. Its CAS number is 13863-41-7, and its EINECS number is 237-601-4. [1]
The hypobromite ion, also called alkaline bromine water, is BrO −. Bromine is in the +1 oxidation state. The Br–O bond length is 1.82 Å. [1] Hypobromite is the bromine compound analogous to hypochlorites found in common bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as hypochlorite, and is also used ...
Bromine dioxide (BrO 2) Bromine can form several different oxides: Dibromine monoxide (Br 2 O) Bromine dioxide (BrO 2) Dibromine trioxide (Br 2 O 3) Dibromine pentoxide (Br 2 O 5) Tribromine octoxide (Br 3 O 8) Also, a number of ions are bromine oxides: Hypobromite (BrO −) Bromite (BrO 2 −) Bromate (BrO 3 −) Perbromate (BrO 4 −) And the ...