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The Buchner ring expansion is a two-step organic C-C bond forming reaction used to access 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate , which cyclopropanates an aromatic ring.
It is commonly thought to be named after the Nobel Laureate Eduard Buchner (without umlaut), but it is actually named after the industrial chemist Ernst Büchner. [2] A Büchner funnel fitted with Sintered Disc made of Boro 3.3 Glass. Diagram of filtration set-up using a Büchner flask
Buchner funnels are made of porcelain and include a plate of sintered glass or perforated porcelain. These are used in filtration under low pressure with a Buchner flask. [2] Hot filtration funnel is a less commonly seen funnel where the funnel is jacketed, and surrounded by a heated fluid. [3]
His father was the pharmacist, chemist, industrialist and politician Wilhelm Büchner.Ernst was also the nephew of the playwright Georg Büchner and the philosopher, physiologist and physician Ludwig Büchner.
Büchner flask A Büchner funnel is attached to the flask via a black elastomer adapter. The hose barb is connected via vacuum hose to a vacuum source such as an aspirator. ...
The Buchner–Curtius–Schlotterbeck reaction is the reaction of aldehydes or ketones with aliphatic diazoalkanes to form homologated ketones. [1] It was first described by Eduard Buchner and Theodor Curtius in 1885 [ 2 ] and later by Fritz Schlotterbeck in 1907. [ 3 ]
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