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Hydrogen isocyanide (HNC) is a linear triatomic molecule with C ∞v point group symmetry.It is a zwitterion and an isomer of hydrogen cyanide (HCN). [2] Both HNC and HCN have large, similar dipole moments, with μ HNC = 3.05 Debye and μ HCN = 2.98 Debye respectively. [3]
It is a colorless salt, similar in appearance to sugar, that is highly soluble in water. Most KCN is used in gold mining, organic synthesis, and electroplating. Smaller applications include jewellery for chemical gilding and buffing. [4] Potassium cyanide is highly toxic, and a dose of 200 to 300 milligrams will kill nearly any human.
Low-temperature photolysis of solids containing HNCO creates the tautomer cyanic acid H−O−C≡N, also called hydrogen cyanate. [15] Pure cyanic acid has not been isolated, and isocyanic acid is the predominant form in all solvents. [2] Sometimes information presented for cyanic acid in reference books is actually for isocyanic acid ...
The overall reaction is: CuSO 4 + 4 Na(C 3 N 3 O 3 Cl 2) → Na 2 [Cu(C 3 N 3 O 3 Cl 2) 4] + Na 2 SO 4. Sodium dichloroisocyanurate reacts with concentrated (130 vol, 35%) hydrogen peroxide to create singlet oxygen which emits red light upon decomposition . [2] It is considered hazardous according to OSHA 29 CFR 1910.1200.
Sodium cyanide is produced by treating hydrogen cyanide with sodium hydroxide: [4] HCN + NaOH → NaCN + H 2 O. Worldwide production was estimated at 500,000 tons in the year 2006. Formerly it was prepared by the Castner process involving the reaction of sodium amide with carbon at elevated temperatures. NaNH 2 + C → NaCN + H 2
The C-N distance in isocyanides is 115.8 pm in methyl isocyanide.The C-N-C angles are near 180°. [3]Akin to carbon monoxide, isocyanides are described by two resonance structures, one with a triple bond between the nitrogen and the carbon and one with a double bond between.
Cyanogen is typically generated from cyanide compounds. One laboratory method entails thermal decomposition of mercuric cyanide: . 2 Hg(CN) 2 → (CN) 2 + Hg 2 (CN) 2 Or, one can combine solutions of copper(II) salts (such as copper(II) sulfate) with cyanides; an unstable copper(II) cyanide is formed which rapidly decomposes into copper(I) cyanide and cyanogen.
Methylidynephosphane can be synthesized via the reaction of phosphine with carbon, [1] but it is extremely reactive and polymerises readily at temperatures above −120 °C. However, several types of derivatives, with bulky groups, such as tert -butyl or trimethylsilyl , substituted for the hydrogen atom, are much more stable, and are useful ...