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Solvent Density (g cm-3) Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; ... List of boiling and freezing information of ...
With various solvents there is a different effect on the electronic ground state and excited state of the solute, so that the size of energy gap between them changes as the solvent changes. This is reflected in the absorption or emission spectrum of the solute as differences in the position, intensity, and shape of the spectroscopic bands .
Reichardt's dye (Betaine 30) is an organic dye belonging to the class of azomerocyanine betaines.This dye is notable for its solvatochromic properties, meaning it changes color depending on the solvent in which it is dissolved.
This arises from the fact that polar solvents stabilize the formation of the carbocation intermediate to a greater extent than the non-polar-solvent conditions. This is apparent in the ΔE a, ΔΔG ‡ activation. On the right is an S N 2 reaction coordinate diagram. Note the decreased ΔG ‡ activation for the non-polar-solvent reaction ...
A polar aprotic solvent is a solvent that lacks an acidic proton and is polar. Such solvents lack hydroxyl and amine groups. In contrast to protic solvents, these solvents do not serve as proton donors in hydrogen bonding, although they can be proton acceptors. Many solvents, including chlorocarbons and hydrocarbons, are classifiable as aprotic ...
The beginning of modern science-based chemical or electrochemical coloring of metals is marked by Leopoldo Nobili's (1784–1835) discovery of Nobilis colored rings in 1826. [10] Leonhard Elsner, Alexander Watt, Antoine César Becquerel (1788–1878) and Rudolf Christian Böttger (1806–1881) are also important people in the early history of ...
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Aromatics, which contain one or more aromatic rings, are slightly more polarizable. The remaining two fractions, resins and asphaltenes, have polar substituents. The distinction between the two is that asphaltenes are insoluble in an excess of heptane (or pentane) whereas resins are miscible with heptane (or pentane).