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A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
For example, if narrow molar mass distribution standards are available for polystyrene, these can be used to construct a calibration curve (typically vs. retention volume ) in eg. toluene at 40 °C. This calibration can then be used to determine the "polystyrene equivalent" molecular weight of a polyethylene sample if the Mark-Houwink ...
Using the calibration curve method, the analyst can calibrate the spectrometer with a pure silver aqueous solutions, and use the calibration graph to determine the amount of silver present in the waste samples. This method, however, assumes the pure aqueous solution of silver and a photographic waste sample have the same matrix and therefore ...
The calibration curve that does not use the internal standard method ignores the uncertainty between measurements. The coefficient of determination (R 2) for this plot is 0.9985. In the calibration curve that uses the internal standard, the y-axis is the ratio of the nickel signal to the yttrium signal.
There are two main uses of the term calibration in statistics that denote special types of statistical inference problems. Calibration can mean a reverse process to regression, where instead of a future dependent variable being predicted from known explanatory variables, a known observation of the dependent variables is used to predict a corresponding explanatory variable; [1]
Fitting of a noisy curve by an asymmetrical peak model, with an iterative process (Gauss–Newton algorithm with variable damping factor α).Curve fitting [1] [2] is the process of constructing a curve, or mathematical function, that has the best fit to a series of data points, [3] possibly subject to constraints.
The calibration curve for the southern hemisphere is known as the SHCal as opposed to the IntCal for the northern hemisphere; the most recent version was published in 2020. There is also a curve for the period after 1955, where radiocarbon levels were artificially inflated due to atomic bomb testing, varying with latitude, known as Bomb Cal. [ 14 ]
The Callendar–Van Dusen equation is an equation that describes the relationship between resistance (R) and temperature (T) of platinum resistance thermometers (RTD). As commonly used for commercial applications of RTD thermometers, the relationship between resistance and temperature is given by the following equations.