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In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.
The Forouhi–Bloomer dispersion equations for n and k were originally expected to apply to semiconductors and dielectrics, whether in amorphous, polycrystalline, or crystalline states. However, they have been shown to describe the n and k spectra of transparent conductors, [5] as well as metallic compounds.
Similarly to Lyman-alpha, the K-alpha emission is composed of two spectral lines, K-alpha 1 (Kα 1) and K-alpha 2 (Kα 2). [6] The K-alpha 1 emission is slightly higher in energy (and, thus, has a lower wavelength) than the K-alpha 2 emission. For all elements, the ratio of the intensities of K-alpha 1 and K-alpha 2 is very close to 2:1. [7]
The higher the temperature of the gas, the wider the distribution of velocities in the gas. Since the spectral line is a combination of all of the emitted radiation, the higher the temperature of the gas, the broader the spectral line emitted from that gas. This broadening effect is described by a Gaussian profile and there is no associated shift.
K-line in spectrometry refers to one of two different spectral features: The calcium K line, one of the pair of Fraunhofer lines in the violet associated with ionised calcium The x-ray peak ( K-line (x-ray) ) associated with iron
According to Planck's distribution law, the spectral energy density (energy per unit volume per unit frequency) at given temperature is given by: [4] [5] (,) = alternatively, the law can be expressed for the spectral radiance of a body for frequency ν at absolute temperature T given as: [6] [7] [8] (,) = where k B is the Boltzmann ...
In atomic physics, Doppler broadening is broadening of spectral lines due to the Doppler effect caused by a distribution of velocities of atoms or molecules. Different velocities of the emitting (or absorbing) particles result in different Doppler shifts, the cumulative effect of which is the emission (absorption) line broadening. [1]
The equivalent width of a spectral line is a measure of the area of the line on a plot of intensity versus wavelength in relation to underlying continuum level. It is found by forming a rectangle with a height equal to that of continuum emission, and finding the width such that the area of the rectangle is equal to the area in the spectral line.