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The caesium chloride structure adopts a primitive cubic lattice with a two-atom basis, where both atoms have eightfold coordination. The chloride atoms lie upon the lattice points at the corners of the cube, while the caesium atoms lie in the holes in the center of the cubes; an alternative and exactly equivalent 'setting' has the caesium ions at the corners and the chloride ion in the center.
Also called the "caesium chloride structure", [31] this structural motif is composed of a primitive cubic lattice with a two-atom basis, each with an eightfold coordination; the chloride atoms lie upon the lattice points at the edges of the cube, while the caesium atoms lie in the holes in the centre of the cubes.
A caesium chloride unit cell. The two colors of spheres represent the two types of atoms. One structure is the "interpenetrating primitive cubic" structure, also called a "caesium chloride" or B2 structure. This structure is often confused for a body-centered cubic structure because the arrangement of atoms is the same.
For chemical compounds with regular lattices such as sodium chloride and caesium chloride, a count of the nearest neighbors gives a good picture of the environment of the ions. In sodium chloride each sodium ion has 6 chloride ions as nearest neighbours (at 276 pm) at the corners of an octahedron and each chloride ion has 6 sodium atoms (also ...
A simple cubic crystal has only one lattice constant, the distance between atoms, but in general lattices in three dimensions have six lattice constants: the lengths a, b, and c of the three cell edges meeting at a vertex, and the angles α, β, and γ between those edges. The crystal lattice parameters a, b, and c have the dimension of length.
Coloured flames of methanol solutions of different compounds, burning on cotton wool. From left to right: lithium chloride, strontium chloride, calcium chloride, sodium chloride, barium chloride, trimethyl borate, copper chloride, cesium chloride and potassium chloride. Some common elements and their corresponding colors are:
In a crystal structure the coordination geometry of an atom is the geometrical pattern of coordinating atoms where the definition of coordinating atoms depends on the bonding model used. [1] For example, in the rock salt ionic structure each sodium atom has six near neighbour chloride ions in an octahedral geometry and each chloride has ...
Repeating units will help to show how easy it is and clear it is to represent molecules through balls that represent atoms. The binary compounds sodium chloride (NaCl) and caesium chloride (CsCl) have cubic structures but have different space groups. This can be rationalised in terms of close packing of spheres of different sizes.