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The nitride anion, N 3-ion, is very elusive but compounds of nitride are numerous, although rarely naturally occurring. Some nitrides have a found applications, [1] such as wear-resistant coatings (e.g., titanium nitride, TiN), hard ceramic materials (e.g., silicon nitride, Si 3 N 4), and semiconductors (e.g., gallium nitride, GaN).
Sodium nitride is the inorganic compound with the chemical formula Na 3 N. In contrast to lithium nitride and some other nitrides , sodium nitride is an extremely unstable alkali metal nitride . It can be generated by combining atomic beams of sodium and nitrogen deposited onto a low-temperature sapphire substrate. [ 1 ]
α-Calcium nitride adopts an anti-bixbyite structure, similar to Mn 2 O 3, except that the positions of the ions are reversed: calcium (Ca 2+) take the oxide (O 2−) positions and nitride ions (N 3−) the manganese (Mn 3+). In this structure, Ca 2+ occupies tetrahedral sites, and the nitride centres occupy two different types of octahedral ...
Gallium nitride (Ga N) is a binary III/V direct bandgap semiconductor commonly used in blue light-emitting diodes since the 1990s. The compound is a very hard material that has a Wurtzite crystal structure .
Silicon nitride is a chemical compound of the elements silicon and nitrogen. Si 3 N 4 (Trisilicon tetranitride) is the most thermodynamically stable and commercially important of the silicon nitrides, [6] and the term ″Silicon nitride″ commonly refers to this specific composition.
The nitrite ion has the chemical formula NO − 2.Nitrite (mostly sodium nitrite) is widely used throughout chemical and pharmaceutical industries. [1] The nitrite anion is a pervasive intermediate in the nitrogen cycle in nature.
Lithium nitride is prepared by direct reaction of elemental lithium with nitrogen gas: [2] 6 Li + N 2 → 2 Li 3 N. Instead of burning lithium metal in an atmosphere of nitrogen, a solution of lithium in liquid sodium metal can be treated with N 2. Lithium nitride must be protected from moisture as it reacts violently with water to produce ammonia:
Manganese nitrides are salts of manganese and the nitride ion. Four of these compounds are stable at atmospheric pressure . The most important is Mn 3 N 2 , which catalyzes nitrogen fixation and is a high-temperature antiferromagnet .