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A spectral line may be observed either as an emission line or an absorption line. Which type of line is observed depends on the type of material and its temperature relative to another emission source. An absorption line is produced when photons from a hot, broad spectrum source pass through a cooler material.
The plot for vapor is a transformation of data Synthetic spectrum for gas mixture ' Pure H 2 O ' (296K, 1 atm) retrieved from Hitran on the Web Information System. [6] Liquid water absorption spectrum across a wide wavelength range [missing source] The absorption of electromagnetic radiation by water depends on the state of the water.
Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum. Ideal line shapes include Lorentzian , Gaussian and Voigt functions, whose parameters are the line position, maximum height and half-width. [ 1 ]
A demonstration of the 589 nm D 2 (left) and 590 nm D 1 (right) emission sodium D lines using a wick with salt water in a flame. The Fraunhofer C, F, G′, and h lines correspond to the alpha, beta, gamma, and delta lines of the Balmer series of emission lines of the hydrogen atom. The Fraunhofer letters are now rarely used for those lines.
A demonstration of the 589 nm D 2 (left) and 590 nm D 1 (right) emission sodium D lines using a wick with salt water in a flame. The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high
The emission spectra of ions are different than of neutral atoms; the ions may emit in undesired spectral ranges. For example, Ba + emits in blue wavelengths. Ionization can be suppressed by addition of an easier-to-ionize metal with weak visible emission of its own, e.g. potassium; the potassium atoms then act as electron donors, neutralizing ...
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Solar spectrum with Fraunhofer lines as it appears visually. A material's absorption spectrum is the fraction of incident radiation absorbed by the material over a range of frequencies of electromagnetic radiation. The absorption spectrum is primarily determined [2] [3] [4] by the atomic and molecular composition of the material.