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Solvation is, in concept, distinct from solubility. Solvation or dissolution is a kinetic process and is quantified by its rate. Solubility quantifies the dynamic equilibrium state achieved when the rate of dissolution equals the rate of precipitation. The consideration of the units makes the distinction clearer.
In chemistry, solvent effects are the influence of a solvent on chemical reactivity or molecular associations. Solvents can have an effect on solubility, stability and reaction rates and choosing the appropriate solvent allows for thermodynamic and kinetic control over a chemical reaction.
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
For interstitial solid solutions, the Hume-Rothery Rules are: . Solute atoms should have a smaller radius than 59% of the radius of solvent atoms. [5] [6]The solute and solvent should have similar electronegativity.
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The Debye–Hückel theory [7] was based on the assumption that each ion was surrounded by a spherical "cloud" or ionic atmosphere made up of ions of the opposite charge. Expressions were derived for the variation of single-ion activity coefficients as a function of ionic strength. This theory was very successful for dilute solutions of 1:1 ...
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