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Diethylaminosulfur trifluoride (DAST) is the organosulfur compound with the formula Et 2 NSF 3. This liquid is a fluorinating reagent used for the synthesis of organofluorine compounds . [ 1 ] The compound is colourless; older samples assume an orange colour.
The mechanism of fluorination by DAST parallels that of sulfur tetrafluoride. Attack of the hydroxyl group of the substrate on sulfur and elimination of hydrogen fluoride lead to an alkoxyaminosulfur difluoride intermediate. Nucleophilic attack by fluoride, either by an S N 1 [5] or S N 2 [6] pathway, leads to the product. Although clean ...
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DAST may refer to: Diethylaminosulfur trifluoride , an organosulfur compound Draw-a-Scientist Test , designed to investigate children's perceptions of the scientist
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This was demonstrated in the synthesis of meso-difluorosuccinate from (L)-tartrate and the synthesis of (D)- and (L)-difluorosuccinate from meso-tartrate. [6] Carbonyl compounds generally react with SF 4 to yield geminal difluorides. Reaction times tend to be on the order of hours and yields are moderate. [7]
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