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The refractive index of materials varies with the wavelength (and frequency) of light. [27] This is called dispersion and causes prisms and rainbows to divide white light into its constituent spectral colors. [28] As the refractive index varies with wavelength, so will the refraction angle as light goes from one material to another.
Snell's law (also known as the Snell–Descartes law, the ibn-Sahl law, [1] and the law of refraction) is a formula used to describe the relationship between the angles of incidence and refraction, when referring to light or other waves passing through a boundary between two different isotropic media, such as water, glass, or air.
A. R. Forouhi and I. Bloomer deduced dispersion equations for the refractive index, n, and extinction coefficient, k, which were published in 1986 [1] and 1988. [2] The 1986 publication relates to amorphous materials, while the 1988 publication relates to crystalline.
The most general form of Cauchy's equation is = + + +,where n is the refractive index, λ is the wavelength, A, B, C, etc., are coefficients that can be determined for a material by fitting the equation to measured refractive indices at known wavelengths.
Refraction at interface. Many materials have a well-characterized refractive index, but these indices often depend strongly upon the frequency of light, causing optical dispersion. Standard refractive index measurements are taken at the "yellow doublet" sodium D line, with a wavelength (λ) of 589 nanometers.
Let the angle of refraction, measured in the same sense, be θ t, where the subscript t stands for transmitted (reserving r for reflected). In the absence of Doppler shifts, ω does not change on reflection or refraction. Hence, by , the magnitude of the wave vector is proportional to the refractive index.
He attempted to relate the polarizing angle to the refractive index of the material, but was frustrated by the inconsistent quality of glasses available at that time. In 1815, Brewster experimented with higher-quality materials and showed that this angle was a function of the refractive index, defining Brewster's law.
Here the coefficient A is an approximation of the short-wavelength (e.g., ultraviolet) absorption contributions to the refractive index at longer wavelengths. Other variants of the Sellmeier equation exist that can account for a material's refractive index change due to temperature, pressure, and other parameters.