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PMMA ignites at 460 °C (860 °F) and burns, forming carbon dioxide, water, carbon monoxide, and low-molecular-weight compounds, including formaldehyde. [17] PMMA transmits up to 92% of visible light (3 mm (0.12 in) thickness), [18] and gives a reflection of about 4% from each of its surfaces due to its refractive index (1.4905 at 589.3 nm). [3]
For the first fifty years, glass was the only material used. The lenses were thin, yet reports of injury were rare. In 1938 perspex (polymethylmethacrylate, or PMMA) began to replace glass in contact lens manufacture. PMMA lenses were easier to produce so the production of glass lenses soon ended. Lenses made of PMMA are called hard lenses. [5]
Two inline skate wheels with different durometer – 85A and 83A Digital Shore hardness tester. The Shore durometer is a device for measuring the hardness of a material, typically of polymers.
Poly(methyl acrylate) (PMA) is a family of organic polymers with the formula (CH 2 CHCO 2 CH 3) n.It is a synthetic acrylate polymer derived from methyl acrylate monomer. The polymers are colorless.
Acrylonitrile styrene acrylate (ASA), also called acrylic styrene acrylonitrile, is an amorphous thermoplastic developed as an alternative to acrylonitrile butadiene styrene (ABS), that has improved weather resistance.
In optics and lens design, the Abbe number, also known as the Vd-number or constringence of a transparent material, is an approximate measure of the material's dispersion (change of refractive index versus wavelength), with high values of Vd indicating low dispersion.
PMAA has a pKa of ~4.8, meaning that at neutral pH the MAA groups in the network are almost entirely deprotonated making it an anionic polymer. PMAA can act as a polyelectrolyte and has the ability to absorb and retain water.
The baking times depend on the SU-8 layer thickness; the thicker the layer, the longer the baking time. The temperature is controlled during the baking in order to reduce stress formation in the thick layer (leading to cracks) as the solvent evaporates. The soft bake is the most important of the bake steps for stress formation.