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The commonly known brand name of PTFE-based composition is Teflon by Chemours, [4] a spin-off from DuPont, which originally invented the compound in 1938. [4] Polytetrafluoroethylene is a fluorocarbon solid , as it is a high- molecular-weight polymer consisting wholly of carbon and fluorine .
A convenient, safe method for generating TFE is the pyrolysis of the sodium salt of pentafluoropropionic acid: [6]. C 2 F 5 CO 2 Na → C 2 F 4 + CO 2 + NaF. The depolymerization reaction – vacuum pyrolysis of PTFE at 650–700 °C (1,200–1,290 °F) in a quartz vessel – is a traditional laboratory synthesis of TFE.
Molecular weight (M.W.) (for molecular compounds) and formula weight (F.W.) (for non-molecular compounds), are older terms for what is now more correctly called the relative molar mass (M r). [8] This is a dimensionless quantity (i.e., a pure number, without units) equal to the molar mass divided by the molar mass constant. [notes 1]
The molar mass is defined as the mass of a given substance divided by the amount of the substance, and is expressed in grams per mol (g/mol). That makes the molar mass an average of many particles or molecules (potentially containing different isotopes ), and the molecular mass the mass of one specific particle or molecule.
Structural formula Molecular weight (g/mol) CAS No. Perfluorobutane sulfonamide: H-FBSA C 4 F 9 SO 2 NH 2: 299.12 30334-69-1 Perfluoropentanesulfonamide: PFPSA C 5 F 11 SO 2 NH 2: 349.12 82765-76-2 Perfluorohexanesulfonamide: PFHxSA C 6 F 13 SO 2 NH 2: 399.13 41997-13-1 Perfluoroheptanesulfonamide: PFHpSA C 7 F 15 SO 2 NH 2: 449.14 82765-77-3 ...
Polychlorotrifluoroethylene (PCTFE or PTFCE) is a thermoplastic chlorofluoropolymer with the molecular formula (CF 2 CClF) n, where n is the number of monomer units in the polymer molecule. It is similar to polytetrafluoroethene (PTFE), except that it is a homopolymer of the monomer chlorotrifluoroethylene (CTFE) instead of tetrafluoroethene.
The molar mass constant, usually denoted by M u, is a physical constant defined as one twelfth of the molar mass of carbon-12: M u = M(12 C)/12. [1] The molar mass of an element or compound is its relative atomic mass (atomic weight) or relative molecular mass (molecular weight or formula weight) multiplied by the molar mass constant.
In dissecting the cylinder, he found a mass of white solid in a quantity similar to that of the tetrafluoroethylene gas. It was determined that this material was a new-to-the-world polymer . Tests showed the substance was resistant to corrosion from most acids, bases and solvents and had better high temperature stability than any other plastic.