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The Van Slyke determination is a chemical test for the determination of amino acids containing a primary amine group. It is named after the biochemist Donald Dexter Van Slyke (1883-1971). [1] One of Van Slyke's first professional achievements was the quantification of amino acids by the Van Slyke determination reaction. [2]
Donald Dexter Van Slyke (March 29, 1883 – May 4, 1971), nicknamed Van, was a Dutch American biochemist. His achievements included the publication of 317 journal articles and 5 books, [ 1 ] as well as numerous awards, among them the National Medal of Science and the first AMA Scientific Achievement Award . [ 1 ]
By contrast, at almost the same time, Donald Van Slyke and G. E. Cullen [79] treated the binding step as an irreversible reaction. The Briggs–Haldane equation was of the same algebraic form as both of the earlier equations, but their derivation is based on the quasi- steady state approximation, which is the concentration of intermediate ...
With nitrous acid, one obtains glycolic acid (van Slyke determination). With methyl iodide, the amine becomes quaternized to give trimethylglycine, a natural product: H 3 N + CH 2 COO − + 3 CH 3 I → (CH 3) 3 N + CH 2 COO − + 3 HI. Glycine condenses with itself to give peptides, beginning with the formation of glycylglycine: [34] 2 H 3 N ...
The Van Slyke pipette, invented by Donald Dexter Van Slyke, is a graduated pipette commonly used in medical technology with serologic pipettes for volumetric analysis ...
Buffer capacity rises to a local maximum at pH = pK a. The height of this peak depends on the value of pK a. Buffer capacity is negligible when the concentration [HA] of buffering agent is very small and increases with increasing concentration of the buffering agent. [3] Some authors show only this region in graphs of buffer capacity. [2]
An increased buffer factor results in a decreased buffering effect, which could lead to the uptake of more CO 2 from the atmosphere, and decreasing the pH even more. [ 2 ] Figure 1: Curves illustrating the molar fraction of carbonate species present in seawater across pH, with salinity set at 5,000ppm, and temperature set to 25 degrees Celsius.
Stephen Smale (born July 15, 1930) is an American mathematician, known for his research in topology, dynamical systems and mathematical economics.He was awarded the Fields Medal in 1966 [2] and spent more than three decades on the mathematics faculty of the University of California, Berkeley (1960–1961 and 1964–1995), where he currently is Professor Emeritus, with research interests in ...