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  2. Reductive elimination - Wikipedia

    en.wikipedia.org/wiki/Reductive_elimination

    Reductive elimination is an elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands. It is the microscopic reverse of oxidative addition, and is often the product-forming step in many catalytic processes. Since oxidative addition and reductive ...

  3. Ellingham diagram - Wikipedia

    en.wikipedia.org/wiki/Ellingham_diagram

    The intersection of two lines implies an oxidation-reduction equilibrium. Reduction using a given reductant is possible at temperatures above the intersection point where the ΔG line of that reductant is lower on the diagram than that of the metallic oxide to be reduced. At the point of intersection the free energy change for the reaction is ...

  4. Oxygen reduction reaction - Wikipedia

    en.wikipedia.org/wiki/Oxygen_reduction_reaction

    Rather than combustion, organisms rely on elaborate sequences of electron-transfer reactions, often coupled to proton transfer. The direct reaction of O 2 with fuel is precluded by the oxygen reduction reaction, which produces water and adenosine triphosphate. Cytochrome c oxidase affects the oxygen reduction reaction by binding O 2 in a heme ...

  5. Heterogeneous water oxidation - Wikipedia

    en.wikipedia.org/wiki/Heterogeneous_Water_Oxidation

    2H 2 O → O 2 + 4H + + 4e − Oxidation (generation of dioxygen) 4H + + 4e − → 2H 2 Reduction (generation of dihydrogen) 2H 2 O → 2H 2 + O 2 Total Reaction Of the two half reactions, the oxidation step is the most demanding because it requires the coupling of 4 electron and proton transfers and the formation of an oxygen-oxygen bond.

  6. Reduction potential - Wikipedia

    en.wikipedia.org/wiki/Reduction_potential

    In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...

  7. Oxidizing and reducing flames - Wikipedia

    en.wikipedia.org/wiki/Oxidizing_and_reducing_flames

    A reducing flame is a flame with insufficient oxygen. It has an opaque yellow or orange color due to carbon or hydrocarbons [3] which bind with (or reduce) the oxygen contained in the materials the flame processes. [2]

  8. Oxidizing agent - Wikipedia

    en.wikipedia.org/wiki/Oxidizing_agent

    The international pictogram for oxidizing chemicals. Dangerous goods label for oxidizing agents. An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent (called the reductant, reducer, or electron donor).

  9. Cross-coupling reaction - Wikipedia

    en.wikipedia.org/wiki/Cross-coupling_reaction

    Many mechanisms exist reflecting the myriad types of cross-couplings, including those that do not require metal catalysts. [7] Often, however, cross-coupling refers to a metal-catalyzed reaction of a nucleophilic partner with an electrophilic partner. Mechanism proposed for Kumada coupling (L = Ligand, Ar = Aryl).