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For example, if the R 2 group is a methyl group and the R 1 group is a trifluoromethyl group, the resulting compound is methyl trifluoromethanesulfonate. Sulfonic esters are used as reagents in organic synthesis, chiefly because the RSO 3 − group is a good leaving group, especially when R is electron-withdrawing.
Methyl methanesulfonate (MMS), also known as methyl mesylate, is an alkylating agent and a carcinogen. It is also a suspected reproductive toxicant, and may also be a skin/sense organ toxicant. [ 1 ] It is used in cancer treatment.
Salts and esters of methanesulfonic acid are known as mesylates (or methanesulfonates, as in ethyl methanesulfonate). It is hygroscopic in its concentrated form. Methanesulfonic acid can dissolve a wide range of metal salts, many of them in significantly higher concentrations than in hydrochloric acid (HCl) or sulfuric acid ( H 2 SO 4 ).
Many sulfate esters are used in detergents, and some are useful reagents. Alkyl sulfates consist of a hydrophobic hydrocarbon chain, a polar sulfate group (containing an anion) and either a cation or amine to neutralize the sulfate group.
Methyl esters are esters of methanol. Subcategories. This category has only the following subcategory. M. Methylsulfates (4 P) Pages in category "Methyl esters" ...
Sulfonic acids can be converted to esters. This class of organic compounds has the general formula R−SO 2 −OR. Sulfonic esters such as methyl triflate are considered good alkylating agents in organic synthesis. Such sulfonate esters are often prepared by alcoholysis of the sulfonyl chlorides: RSO 2 Cl + R′OH → RSO 2 OR′ + HCl
It is the ethyl ester of methanesulfonic acid. A colorless liquid, it is classified as an alkylating agent. EMS is the most commonly used chemical mutagen in experimental genetics. [4] [5] Mutations induced by EMS exposure can then be studied in genetic screens or other assays.
Methyl trifluoromethanesulfonate, also commonly called methyl triflate and abbreviated MeOTf, is the organic compound with the formula CF 3 SO 2 OCH 3. It is a colourless liquid which finds use in organic chemistry as a powerful methylating agent. [2] The compound is closely related to methyl fluorosulfonate (FSO 2 OCH 3).