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Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The diffusion equation is a parabolic partial differential equation. In physics, it describes the macroscopic behavior of many micro-particles in Brownian motion , resulting from the random movements and collisions of the particles (see Fick's laws of diffusion ).
"Bulk flow" is the movement/flow of an entire body due to a pressure gradient (for example, water coming out of a tap). "Diffusion" is the gradual movement/dispersion of concentration within a body with no net movement of matter. An example of a process where both bulk motion and diffusion occur is human breathing. [2]
The convection–diffusion equation can be derived in a straightforward way [4] from the continuity equation, which states that the rate of change for a scalar quantity in a differential control volume is given by flow and diffusion into and out of that part of the system along with any generation or consumption inside the control volume: + =, where j is the total flux and R is a net ...
The self-diffusion coefficient of neat water is: 2.299·10 −9 m 2 ·s −1 at 25 °C and 1.261·10 −9 m 2 ·s −1 at 4 °C. [2] Chemical diffusion occurs in a presence of concentration (or chemical potential) gradient and it results in net transport of mass. This is the process described by the diffusion equation.
Graham's law of effusion (also called Graham's law of diffusion) was formulated by Scottish physical chemist Thomas Graham in 1848. [1] Graham found experimentally that the rate of effusion of a gas is inversely proportional to the square root of the molar mass of its particles . [ 1 ]
Multicomponent diffusion is diffusion in mixtures, and diffusiophoresis is the special case where we are interested in the movement of one species that is usually a colloidal particle, in a gradient of a much smaller species, such as dissolved salt such as sodium chloride in water. or a miscible liquid, such as ethanol in water.
In fluid dynamics, eddy diffusion, eddy dispersion, or turbulent diffusion is a process by which fluid substances mix together due to eddy motion. These eddies can vary widely in size, from subtropical ocean gyres down to the small Kolmogorov microscales , and occur as a result of turbulence (or turbulent flow).