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Protodeboronation is a chemical reaction involving the protonolysis of a boronic acid (or other organoborane compound) in which a carbon-boron bond is broken and replaced with a carbon-hydrogen bond. Protodeboronation is a well-known undesired side reaction , and frequently associated with metal-catalysed coupling reactions that utilise boronic ...
This page provides supplementary chemical data on boric acid. Thermodynamic properties. Phase behavior Triple point? K (? °C), ? Pa Critical point? K (? °C), ?
Boric acid is added to borax for use as welding flux by blacksmiths. [39] Boric acid, in combination with polyvinyl alcohol (PVA) or silicone oil, is used to manufacture Silly Putty. [40] Boric acid is also present in the list of chemical additives used for hydraulic fracturing (fracking) in the Marcellus Shale in Pennsylvania. [41]
Phenylboronic acid or benzeneboronic acid, abbreviated as PhB(OH) 2 where Ph is the phenyl group C 6 H 5 - and B(OH) 2 is a boronic acid containing a phenyl substituent and two hydroxyl groups attached to boron. Phenylboronic acid is a white powder and is commonly used in organic synthesis. Boronic acids are mild Lewis acids which are generally ...
Butanoic acid CH 3 (CH 2) 2 COOH C4:0 Valeric acid: Pentanoic acid CH 3 (CH 2) 3 COOH C5:0 Caproic acid: Hexanoic acid CH 3 (CH 2) 4 COOH C6:0 Enanthic acid: Heptanoic acid CH 3 (CH 2) 5 COOH C7:0 Caprylic acid: Octanoic acid CH 3 (CH 2) 6 COOH C8:0 Pelargonic acid: Nonanoic acid CH 3 (CH 2) 7 COOH C9:0 Capric acid: Decanoic acid CH 3 (CH 2) 8 ...
Borinic acid, also known as boronous acid, is an oxyacid of boron with formula H 2 BOH. Borinate is the associated anion of borinic acid with formula H 2 BO −; however, being a Lewis acid, the form in basic solution is H 2 B(OH) − 2. Borinic acid can be formed as the first step in the hydrolysis of diborane: [1] BH 3 + H 2 O → H 2 BOH + H 2
The reaction of boron trichloride with alcohols was reported in 1931, and was used to prepare dimethoxyboron chloride, B(OCH 3) 2 Cl. [3] Egon Wiberg and Wilhelm Ruschmann used it to prepare tetrahydroxydiboron by first introducing the boron–boron bond by reduction with sodium and then hydrolysing the resulting tetramethoxydiboron, B 2 (OCH 3) 4, to produce what they termed sub-boric acid. [4]
One of the most attractive features of the Petasis reaction is the stability of the vinyl boronic acids. With the advent of the Suzuki coupling, many are commercially available. organoboronic acid synthesis. Other methods of generating boronic acids were also reported. [8] [9]