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For example, if the feed is a saturated liquid, q = 1 and the slope of the q-line is infinite (drawn as a vertical line). As another example, if the feed is saturated vapor, q = 0 and the slope of the q-line is 0 (a horizontal line). [2] The typical McCabe–Thiele diagram in Figure 1 uses a q-line representing a partially vaporized feed.
Fractionation at total reflux. The Fenske equation in continuous fractional distillation is an equation used for calculating the minimum number of theoretical plates required for the separation of a binary feed stream by a fractionation column that is being operated at total reflux (i.e., which means that no overhead product distillate is being withdrawn from the column).
The values of the ratio K i are correlated empirically or theoretically in terms of temperature, pressure and phase compositions in the form of equations, tables or graph such as the DePriester charts. [5] K-Values for systems of light hydrocarbons Low Temperature Range K-Values for systems of light hydrocarbons High Temperature Range
The calculation process requires the availability of a great deal of vapor–liquid equilibrium data for the components present in the distillation feed, and the calculation procedure is very complex. [2] [3] In an industrial distillation column, the N t required to achieve a given separation also depends upon the amount of reflux used. Using ...
The Thiele Modulus was developed to describe the relationship between diffusion and reaction rates in porous catalyst pellets with no mass transfer limitations. This value is generally used to measure the effectiveness factor of pellets. The Thiele modulus is represented by different symbols in different texts, but is defined in Hill [2] as h T.
This is a diagram exemplifying how the en:McCabe-Thiele method is used to determine the number of theoretical equilibrium stages required in a distillation unit. Licensing I, the copyright holder of this work, hereby publish it under the following license:
Warren Lee McCabe (August 7, 1899 – August 24, 1982) was an American Physical Chemist and is considered as one of the founding fathers of the profession of chemical engineering. [1] He is widely known for the eponymous McCabe–Thiele method for analysis of distillation processes and his book, Unit Operations of Chemical Engineering , a major ...
The McCabe-Thiele diagram is not just for distillation. It is also used (and very pertinent) to solvent extraction, where two liquids contact each other to exchange solute species. Somebody that knows about the solvent extraction field needs to add this technology as an application of the M-T diagram, and create a link to the Wikipedia liquid ...