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By mathematically modeling the rate of diffusion of water in the material and the rate of degradation of the material, it is possible to predict whether a certain material will undergo surface or bulk erosion by looking at the ratio between the two rates. The rate of diffusion of water is modeled by the equation
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
For example, if the initial population of the assembly, N(0), is 1000, then the population at time , (), is 368. A very similar equation will be seen below, which arises when the base of the exponential is chosen to be 2, rather than e. In that case the scaling time is the "half-life".
This has the same form as an equation for a straight line: = +, where x is the reciprocal of T. So, when a reaction has a rate constant obeying the Arrhenius equation, a plot of ln k versus T −1 gives a straight line, whose slope and intercept can be used to determine E a and A respectively. This procedure is common in experimental chemical ...
Half-life is constant over the lifetime of an exponentially decaying quantity, and it is a characteristic unit for the exponential decay equation. The accompanying table shows the reduction of a quantity as a function of the number of half-lives elapsed.
L. M. Kachanov [5] and Y. N. Rabotnov [6] suggested the following evolution equations for the creep strain ε and a lumped damage state variable ω: ˙ = ˙ ˙ = ˙ where ˙ is the creep strain rate, ˙ is the creep-rate multiplier, is the applied stress, is the creep stress exponent of the material of interest, ˙ is the rate of damage accumulation, ˙ is the damage-rate multiplier, and is ...
In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. [1]
The Universal Soil Loss Equation (USLE) is a widely used mathematical model that describes soil erosion processes. [1]Erosion models play critical roles in soil and water resource conservation and nonpoint source pollution assessments, including: sediment load assessment and inventory, conservation planning and design for sediment control, and for the advancement of scientific understanding.