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Vinyl ester resin is extensively used to manufacture FRP tanks and vessels as per BS4994. For laminating process, vinyl ester is usually initiated with methyl ethyl ketone peroxide. It has greater strength and mechanical properties than polyester and less than epoxy resin. Renewable precursors to vinyl ester resins have been developed. [2]
The price of the vinyl ester resin is similar to that of the polyester resin. It utilizes the same hardeners as polyester resin (at a similar mix ratio). It doesn't degrade much over time, when compared to polyester resin, and is more flexible. Generally, vinyl ester resin is considered as fuel resistant.
Vinyl ester resin is an example of a synthetic resin. [1] Synthetic resins are industrially produced resins, typically viscous substances that convert into rigid polymers by the process of curing. In order to undergo curing, resins typically contain reactive end groups, [2] such as acrylates or epoxides.
Vinyl ester resins made by addition reactions between an epoxy resin with acrylic acid derivatives, when diluted/dissolved in a vinyl functional monomer such as styrene, polymerise. The resulting thermosets are notable for their high adhesion, heat resistance and corrosion resistance.
Polyester resin offers the following advantages: Adequate resistance to water and variety of chemicals. Adequate resistance to weathering and ageing. Low cost. Polyesters can withstand a temperature up to 80 °C. Polyesters have good wetting to glass fibres. Relatively low shrinkage at between 4–8% during curing.
SMC is both a process and reinforced composite material. This is manufactured by dispersing long strands (usually >1”) of chopped fiber, commonly glass fibers or carbon fibers on a bath of thermoset resin (typically polyester resin, vinyl ester resin or epoxy resin).
Vinyl ester refers to esters formally derived from vinyl alcohol. Commercially important examples of these monomers are vinyl acetate, vinyl propionate, ...
The most common resin system used for the spray-up process is general purpose or DCDP polyester; isophthalic polyesters and vinyl ester resins are also sometimes used. Fast-reacting resins with a pot life of 30 to 40 minutes are typical. The resin often contains a significant amount of filler.