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In quantum mechanics, an atomic orbital (/ ˈɔːrbɪtəl /) is a function describing the location and wave-like behavior of an electron in an atom. [1] This function describes an electron's charge distribution around the atom's nucleus, and can be used to calculate the probability of finding an electron in a specific region around the nucleus.
This notation is used to specify electron configurations and to create the term symbol for the electron states in a multi-electron atom. When writing a term symbol, the above scheme for a single electron's orbital quantum number is applied to the total orbital angular momentum associated to an electron state.
A quantum number beginning in n = 3,ℓ = 0, describes an electron in the s orbital of the third electron shell of an atom. In chemistry, this quantum number is very important, since it specifies the shape of an atomic orbital and strongly influences chemical bonds and bond angles. The azimuthal quantum number can also denote the number of ...
Term symbol. In atomic physics, a term symbol is an abbreviated description of the total spin and orbital angular momentum quantum numbers of the electrons in a multi-electron atom. So while the word symbol suggests otherwise, it represents an actual value of a physical quantity. For a given electron configuration of an atom, its state depends ...
Magnetic quantum number. In atomic physics, a magnetic quantum number is a quantum number used to distinguish quantum states of an electron or other particle according to its angular momentum along a given axis in space. The orbital magnetic quantum number (ml or m[a]) distinguishes the orbitals available within a given subshell of an atom.
The maximum number of electrons in any shell is 2n 2, where n is the principal quantum number. The maximum number of electrons in a subshell is equal to 2(2 l + 1), where the azimuthal quantum number l is equal to 0, 1, 2, and 3 for s, p, d, and f subshells, so that the maximum numbers of electrons are 2, 6, 10, and 14 respectively.
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