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2,3-sigmatropic rearrangements can offer high stereoselectivity. At the newly formed double bond there is a strong preference for formation of the E-alkene or trans isomer product. The stereochemistry of the newly formed C-C bond is harder to predict. It can be inferred from the five-membered ring transition state.
2,3,3-Trimethylpentane is a chemical compound in the family of hydrocarbons which has a formula of C 8 H 18. It is an isomer of octane . It has a role as a human metabolite, a bacterial metabolite and a mammalian metabolite. [ 2 ]
2,3-Epoxybutane is an organic compound with the formula CH 3 CH(O)CHCH 3. It is an epoxide . The compound exists as three stereoisomers , a pair of enantiomers and the meso isomer .
Another example is O(SiH 3) 2 with an Si–O–Si angle of 144.1°, which compares to the angles in Cl 2 O (110.9°), (CH 3) 2 O (111.7°), and N(CH 3) 3 (110.9°). [24] Gillespie and Robinson rationalize the Si–O–Si bond angle based on the observed ability of a ligand's lone pair to most greatly repel other electron pairs when the ligand ...
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms. [1]
The [2,3]-Wittig rearrangement is the transformation of an allylic ether into a homoallylic alcohol via a concerted, pericyclic process. Because the reaction is concerted, it exhibits a high degree of stereocontrol, and can be employed early in a synthetic route to establish stereochemistry.
Common name IUPAC name Molecular formula Structural formula citric acid: 2-hydroxypropane-1,2,3-tricarboxylic acid: C 6 H 8 O 7: isocitric acid: 1-hydroxypropane-1,2,3-tricarboxylic acid