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Boltzmann constant: The Boltzmann constant, k, is one of seven fixed constants defining the International System of Units, the SI, with k = 1.380 649 x 10 −23 J K −1. The Boltzmann constant is a proportionality constant between the quantities temperature (with unit kelvin) and energy (with unit joule).
kT (also written as k B T) is the product of the Boltzmann constant, k (or k B), and the temperature, T.This product is used in physics as a scale factor for energy values in molecular-scale systems (sometimes it is used as a unit of energy), as the rates and frequencies of many processes and phenomena depend not on their energy alone, but on the ratio of that energy and kT, that is, on E ...
This link is provided by Boltzmann's fundamental assumption written as S = k B ln Ω , {\displaystyle S=k_{\rm {B}}\ln \Omega ,} where k B is the Boltzmann constant , S is the classical thermodynamic entropy, and Ω is the number of microstates.
These include the Boltzmann constant, which gives the correspondence of the dimension temperature to the dimension of energy per degree of freedom, and the Avogadro constant, which gives the correspondence of the dimension of amount of substance with the dimension of count of entities (the latter formally regarded in the SI as being dimensionless).
where is the Boltzmann constant (also written as simply ) and equal to 1.380649 × 10 −23 J/K, and is the natural logarithm function (or log base e, as in the image above). In short, the Boltzmann formula shows the relationship between entropy and the number of ways the atoms or molecules of a certain kind of thermodynamic system can be arranged.
where k B is the Boltzmann constant and e is the elementary charge. This empirical law is named after Gustav Wiedemann and Rudolph Franz, who in 1853 reported that κ/σ has approximately the same value for different metals at the same temperature. [2] The proportionality of κ/σ with temperature was discovered by Ludvig Lorenz in 1872. [3]
The proportionality constant k B is one of the fundamental constants of physics and is named the Boltzmann constant in honor of its discoverer. Boltzmann's entropy describes the system when all the accessible microstates are equally likely. It is the configuration corresponding to the maximum of entropy at equilibrium.
The Boltzmann constant also relates the thermodynamic temperature of a gas to the mean kinetic energy of an individual particles' translational motion as follows: ~ = where: ~ is the mean kinetic energy for an individual particle; k B = 1.380 649 × 10 −23 J/K