Search results
Results From The WOW.Com Content Network
The limiting current in electrochemistry is the limiting value of a faradaic current that is approached as the rate of charge transfer to an electrode is increased. The limiting current can be approached, for example, by increasing the electric potential or decreasing the rate of mass transfer to the electrode. It is independent of the applied ...
Any transient current that may be flowing is considered non-faradaic. [1] The reason for this behavior is that the electrode reaction is infinitely slow, with zero exchange current density, and behaves electrically as a capacitor. The concept of the ideal polarizability has been first introduced by F.O. Koenig in 1934. [1]
Pseudocapacitive processes lead to a charge-dependent, linear capacitive behavior, as well as the accomplishment of non-faradaic double-layer capacitance in contrast to batteries, which have a nearly charge-independent behavior. The amount of pseudocapacitance depends on the surface area, material and structure of the electrodes.
Faradaic efficiency of a cell design is usually measured through bulk electrolysis where a known quantity of reagent is stoichiometrically converted to product, as measured by the current passed. This result is then compared to the observed quantity of product measured through another analytical method.
Faraday discovered that when the same amount of electric current is passed through different electrolytes connected in series, the masses of the substances deposited or liberated at the electrodes are directly proportional to their respective chemical equivalent/equivalent weight (E). [3]
Double-pulsed chronoamperometry waveform showing integrated region for charge determination.. In electrochemistry, chronoamperometry is an analytical technique in which the electric potential of the working electrode is stepped and the resulting current from faradaic processes occurring at the electrode (caused by the potential step) is monitored as a function of time.
The exponential decay of the capacitive current is much more rapid than the decay of the faradaic current; hence, the faradaic current is proportionally larger at the end of the drop life. Unfortunately, this process is complicated by the continuously changing potential that is applied to the working electrode (the Hg drop) throughout the ...
The magnetic Lorentz force v × B drives a current along the conducting radius to the conducting rim, and from there the circuit completes through the lower brush and the axle supporting the disc. This device generates an emf and a current, although the shape of the "circuit" is constant and thus the flux through the circuit does not change ...