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log 10 β values between about 2 and 11 can be measured directly by potentiometric titration using a glass electrode. This enormous range of stability constant values (ca. 100 to 10 11) is possible because of the logarithmic response of the electrode. The limitations arise because the Nernst equation breaks down at very low or very high pH.
The apparent dimension of this K value is concentration 1−p−q; this may be written as M (1−p−q) or mM (1−p−q), where the symbol M signifies a molar concentration (1M = 1 mol dm −3). The apparent dimension of a dissociation constant is the reciprocal of the apparent dimension of the corresponding association constant , and vice versa .
For a reversible reaction, the equilibrium constant can be measured at a variety of temperatures. This data can be plotted on a graph with ln K eq on the y-axis and 1 / T on the x axis. The data should have a linear relationship, the equation for which can be found by fitting the data using the linear form of the Van 't Hoff equation
A mathematical constant is a key number whose value is fixed by an unambiguous definition, often referred to by a symbol (e.g., an alphabet letter), or by mathematicians' names to facilitate using it across multiple mathematical problems. [1]
Since ε 2 = 0 for dual numbers, exp(aε) = 1 + aε, all other terms of the exponential series vanishing. Let F = {1 + εr : r ∈ H}, ε 2 = 0. Note that F is stable under the rotation q → p −1 qp and under the translation (1 + εr)(1 + εs) = 1 + ε(r + s) for any vector quaternions r and s. F is a 3-flat in the eight-dimensional space of ...
The chelate effect increases as the number of chelate rings increases. For example, the complex [Ni(dien) 2)] 2+ is more stable than the complex [Ni(en) 3)] 2+; both complexes are octahedral with six nitrogen atoms around the nickel ion, but dien (diethylenetriamine, 1,4,7-triazaheptane) is a tridentate ligand and en is bidentate. The number of ...
Every probability space gives rise to a measure which takes the value 1 on the whole space (and therefore takes all its values in the unit interval [0, 1]). Such a measure is called a probability measure or distribution. See the list of probability distributions for instances. The Dirac measure δ a (cf. Dirac delta function) is given by δ a ...
A traditional Aristotelian realist philosophy of mathematics, stemming from Aristotle and remaining popular until the eighteenth century, held that mathematics is the "science of quantity". Quantity was considered to be divided into the discrete (studied by arithmetic) and the continuous (studied by geometry and later calculus ).