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Schrock alkylidenes for olefin metathesis of the type Mo(NAr)(CHC(CH 3) 2 R){OC(CH 3)(CF 3) 2} 2 were commercialized starting in 1990. [47] [48] The first asymmetric catalyst followed in 1993 [49] With a Schrock catalyst modified with a BINOL ligand in a norbornadiene ROMP leading to highly stereoregular cis, isotactic polymer.
Avoid cooking under cabinet overhangs, as the rising steam from the cooker can damage your cabinets. Check for cracks: Before cooking, inspect all parts of your cooker for cracks or damage, which ...
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Schrock carbenes do not have π-accepting ligands on the metal centre. They are often called alkylidene complexes. Typically this subset of carbene complexes are found with: [6] high oxidation state metal center; early transition metals Ti(IV), Ta(V) σ-donor and sometimes π-donor metal ligands; hydrogen and alkyl substituents on carbenoid carbon.
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