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  2. Cyanometalate - Wikipedia

    en.wikipedia.org/wiki/Cyanometalate

    Cyanometallates or cyanometalates are a class of coordination compounds, most often consisting only of cyanide ligands. [1] Most are anions. Cyanide is a highly basic and small ligand, hence it readily saturates the coordination sphere of metal ions.

  3. Coordination complex - Wikipedia

    en.wikipedia.org/wiki/Coordination_complex

    Cisplatin, PtCl 2 (NH 3) 2, is a coordination complex of platinum(II) with two chloride and two ammonia ligands.It is one of the most successful anticancer drugs. A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands ...

  4. Coordinate covalent bond - Wikipedia

    en.wikipedia.org/wiki/Coordinate_covalent_bond

    In coordination chemistry, a coordinate covalent bond, [1] also known as a dative bond, [2] dipolar bond, [1] or coordinate bond [3] is a kind of two-center, two-electron covalent bond in which the two electrons derive from the same atom. The bonding of metal ions to ligands involves this kind of interaction. [4]

  5. IUPAC nomenclature of inorganic chemistry 2005 - Wikipedia

    en.wikipedia.org/wiki/IUPAC_nomenclature_of...

    Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005 is the 2005 version of Nomenclature of Inorganic Chemistry (which is informally called the Red Book). It is a collection of rules for naming inorganic compounds, as recommended by the International Union of Pure and Applied Chemistry (IUPAC).

  6. Transition metal isocyanide complexes - Wikipedia

    en.wikipedia.org/wiki/Transition_metal_iso...

    Trifluoromethylisocyanide is the exception, its coordination properties are very similarly to those of CO. Because the CNC linkage is linear, the cone angle of these ligands is small, so it is easy to prepare polyisocyanide complexes. Many complexes of isocyanides show high coordination numbers, e.g. the eight-coordinate cation [Nb(CNBu−t) 6 ...

  7. Ligand - Wikipedia

    en.wikipedia.org/wiki/Ligand

    In coordination chemistry, a ligand [a] is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electron pairs , often through Lewis bases . [ 1 ]

  8. Chemical nomenclature - Wikipedia

    en.wikipedia.org/wiki/Chemical_nomenclature

    Because the S 2− anion has a subscript of 2 in the formula (giving a 4− charge), the compound must be balanced with a 4+ charge on the Pb cation (lead can form cations with a 4+ or a 2+ charge). Thus, the compound is made of one Pb 4+ cation to every two S 2− anions, the compound is balanced, and its name is written as lead(IV) sulfide.

  9. Transition metal dioxygen complex - Wikipedia

    en.wikipedia.org/wiki/Transition_metal_dioxygen...

    Dioxygen complexes are coordination compounds that contain O 2 as a ligand. [1] [2] The study of these compounds is inspired by oxygen-carrying proteins such as myoglobin, hemoglobin, hemerythrin, and hemocyanin. [3] Several transition metals form complexes with O 2, and many of these complexes form reversibly. [4]