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The polymer solution casting process utilizes a mandrel, or inner diameter mold, that is immersed in a tank of polymer solution or liquid plastic that has been specifically engineered for the process. Due to a combination of thermal and frictional properties, the polymer solution then forms a thin film around the mold. [1]
PVDF may be synthesized from the gaseous vinylidene fluoride (VDF) monomer by a free-radical (or controlled-radical) polymerization process. This may be followed by processes such as melt casting, or processing from a solution (e.g. solution casting, spin coating, and film casting). Langmuir–Blodgett films have also been made.
Extruded film can be stretched, thinned, or oriented in one or two directions. Blown or tubular process forces air into an extruded ring to expand the film. Flat tenter frames stretch the extruded film before annealing. [3] [4] Calender rolls can be used to form film from hot polymers [5] Solution deposition is another film forming process.
In solvent casting and particulate leaching (SCPL), a polymer is dissolved in an organic solvent. Particles, mainly salts, with specific dimensions are then added to the solution. The mixture is shaped into its final geometry. For example, it can be cast onto a glass plate to produce a membrane or in a three-dimensional mold to produce a scaffold.
This process is the same as a regular extrusion process up until the die. There are three main types of dies used in this process: annular (or crosshead), spider, and spiral. Annular dies are the simplest, and rely on the polymer melt channeling around the entire cross section of the die before exiting the die; this can result in uneven flow.
This process not only reduces the cross section of the polymer fiber, but also increases the strength of the fibers by aligning the individual polymer molecules. Before drawing, polymer melt is pushed through a die with a large number of small holes, known as a spinneret. Typically, the fibers are air cooled without any need for curing.
This process is known as insert moulding and allows single parts to contain multiple materials. This process is often used to create plastic parts with protruding metal screws so they can be fastened and unfastened repeatedly. This technique can also be used for In-mould labelling and film lids may also be attached to moulded plastic containers.
Alternately, resin casting may be accomplished with a resin plus a nearly equal amount of a "hardener" liquid (as in many epoxy resin or polyester resin systems), which functionally contains a second polymer, for use in forming a final product plastic which is a copolymer. Copolymers contain two different alternating chemical entities in the ...