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The Michaelis–Arbuzov reaction is the chemical reaction of a trivalent phosphorus ester with an alkyl halide to form a pentavalent phosphorus species and another alkyl halide. Commonly, the phosphorus substrate is a phosphite ester (P(OR) 3) and the alkylating agent is an alkyl iodide. [11] The mechanism of the Michaelis–Arbuzov reaction
Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine. Under standard conditions, it is a white, water-soluble solid comprising a 1:1 mix of sodium cations (Na +) and iodide anions (I −) in a crystal lattice. It is used mainly as a nutritional supplement and in organic chemistry.
Phosphonium iodide is a chemical compound with the formula PH 4 I. It is an example of a salt containing an unsubstituted phosphonium cation (PH + 4). Phosphonium iodide is commonly used as storage for phosphine [2] and as a reagent for substituting phosphorus into organic molecules. [3]
Another shorthand structural diagram is the skeletal formula (also known as a bond-line formula or carbon skeleton diagram). In a skeletal formula, carbon atoms are not signified by the symbol C but by the vertices of the lines. Hydrogen atoms bonded to carbon are not shown—they can be inferred by counting the number of bonds to a particular ...
It would appear that violet phosphorus is a polymer of high relative molecular mass, which on heating breaks down into P 2 molecules. On cooling, these would normally dimerize to give P 4 molecules (i.e. white phosphorus) but, in a vacuum , they link up again to form the polymeric violet allotrope.
Hence hydroiodic acid cannot be concentrated past this point by evaporation of water. [5] Unlike hydrogen fluoride, anhydrous liquid hydrogen iodide is difficult to work with as a solvent, because its boiling point is low, it has a small liquid range, its dielectric constant is low and it does not dissociate appreciably into H 2 I + and HI −
The low solubility of silver iodide and lead iodide reflects the covalent character of these metal iodides. A test for the presence of iodide ions is the formation of yellow precipitates of these compounds upon treatment of a solution of silver nitrate or lead(II) nitrate. [2] Aqueous solutions of iodide salts dissolve iodine better than pure ...
Sodium phosphate; see trisodium phosphate – Na 3 PO 4; Sodium selenate – Na 2 O 4 Se; Sodium selenide – Na 2 Se; Sodium selenite – Na 2 SeO 3; Sodium silicate – Na 2 SiO 3; Sodium sulfate – Na 2 SO 4; Sodium sulfide – Na 2 S; Sodium sulfite – Na 2 SO 3; Sodium tartrate – C 4 H 4 Na 2 O 6; Sodium tellurite – Na 2 TeO 3 ...