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Wave-like behavior of matter has been experimentally demonstrated, first for electrons in 1927 and for other elementary particles, neutral atoms and molecules in the years since. Matter waves have more complex velocity relations than solid objects and they also differ from electromagnetic waves (light).
In the late 17th century, Sir Isaac Newton had advocated that light was corpuscular (particulate), but Christiaan Huygens took an opposing wave description. While Newton had favored a particle approach, he was the first to attempt to reconcile both wave and particle theories of light, and the only one in his time to consider both, thereby anticipating modern wave-particle duality.
The Davisson–Germer experiment confirmed the de Broglie hypothesis that matter has wave-like behavior. This, in combination with the Compton effect discovered by Arthur Compton (who won the Nobel Prize for Physics in 1927), [9] established the wave–particle duality hypothesis which was a fundamental step in quantum theory.
In modern physics, the double-slit experiment demonstrates that light and matter can exhibit behavior of both classical particles and classical waves.This type of experiment was first performed by Thomas Young in 1801, as a demonstration of the wave behavior of visible light. [1]
This behavior is known as wave–particle duality. In addition to light, electrons, atoms, and molecules are all found to exhibit the same dual behavior when fired towards a double slit. [2] A (simplified) diagram of Quantum Tunneling, a phenomenon by which a particle may move through a barrier which would be impossible under classical mechanics.
The concept of wave–particle duality says that neither the classical concept of "particle" nor of "wave" can fully describe the behavior of quantum-scale objects, either photons or matter. Wave–particle duality is an example of the principle of complementarity in quantum physics.
Atomic orbitals are basic building blocks of the atomic orbital model (or electron cloud or wave mechanics model), a modern framework for visualizing submicroscopic behavior of electrons in matter. In this model, the electron cloud of an atom may be seen as being built up (in approximation) in an electron configuration that is a product of ...
Wave functions are not always the most convenient way to describe quantum systems and their behavior. When the preparation of a system is only imperfectly known, or when the system under investigation is a part of a larger whole, density matrices may be used instead.