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The commonly used standard cell has a width of 1 cm [clarify], and thus for very pure water in equilibrium with air would have a resistance of about 10 6 ohms, known as a megohm. Ultra-pure water could achieve 18 megohms or more. Thus in the past, megohm-cm was used, sometimes abbreviated to "megohm".
The siemens (symbol: S) is the unit of electric conductance, electric susceptance, and electric admittance in the International System of Units (SI). Conductance, susceptance, and admittance are the reciprocals of resistance, reactance, and impedance respectively; hence one siemens is equal to the reciprocal of one ohm (Ω −1) and is also referred to as the mho.
Ultrapure water (UPW), high-purity water or highly purified water (HPW) is water that has been purified to uncommonly stringent specifications. Ultrapure water is a term commonly used in manufacturing to emphasize the fact that the water is treated to the highest levels of purity for all contaminant types, including: organic and inorganic compounds; dissolved and particulate matter; volatile ...
where TDS is expressed in mg/L and EC is the electrical conductivity in microsiemens per centimeter at 25 °C. The conversion factor k e varies between 0.55 and 0.8. [5] Some TDS meters use an electrical conductivity measurement to the ppm using the above formula. Regarding units, 1 ppm indicates 1 mg of dissolved solids per 1,000 g of water. [6]
If this convention is used, then the values are in the same range as monovalent ions, e.g. 59.5 S cm 2 mol −1 for 1 / 2 Ca 2+ and 80.0 S cm 2 mol −1 for 1 / 2 SO 2− 4. [4] From the ionic molar conductivities of cations and anions, effective ionic radii can be calculated using the concept of Stokes radius.
In water solutions containing relatively small quantities of dissolved solute (as in biology), such figures may be "percentivized" by multiplying by 100 a ratio of grams solute per mL solution. The result is given as "mass/volume percentage". Such a convention expresses mass concentration of 1 gram of solute in 100 mL of solution, as "1 m/v %".
j is the imaginary unit (i.e. j 2 = −1); and B is the real-valued susceptance, measured in siemens. The admittance ( Y ) is the reciprocal of the impedance ( Z ), if the impedance is not zero:
Here, 1 / f eq can have a fractional (non-integer) value. In precipitation reactions, the equivalence factor measures the number of ions which will precipitate in a given reaction. Here, 1 / f eq is an integer value. Normal concentration of an ionic solution is also related to conductivity (electrolytic) through the use of ...