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Aqueous solutions prepared from copper(II) chloride contain a range of copper(II) complexes depending on concentration, temperature, and the presence of additional chloride ions. These species include the blue color of [Cu(H 2 O) 6 ] 2+ and the yellow or red color of the halide complexes of the formula [CuCl 2+ x ] x − .
The same hydrochloric acid solutions also react with acetylene gas to form [CuCl(C 2 H 2)]. Ammoniacal solutions of CuCl react with acetylenes to form the explosive copper(I) acetylide, Cu 2 C 2. Alkene complexes of CuCl can be prepared by reduction of CuCl 2 by sulfur dioxide in the presence of the alkene in alcohol solution.
Calcium chloride was apparently discovered in the 15th century but wasn't studied properly until the 18th century. [11] It was historically called "fixed sal ammoniac" (Latin: sal ammoniacum fixum [12]) because it was synthesized during the distillation of ammonium chloride with lime and was nonvolatile (while the former appeared to sublime); in more modern times (18th-19th cc.) it was called ...
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
Copper(II) acetate, also referred to as cupric acetate, is the chemical compound with the formula Cu(OAc) 2 where AcO − is acetate (CH 3 CO − 2).The hydrated derivative, Cu 2 (OAc) 4 (H 2 O) 2, which contains one molecule of water for each copper atom, is available commercially.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Legend: (g)—gas; (l)—liquid; (aq)—aqueous solution; the balance of the species are in a solid phase. Atomic Energy of Canada Limited has demonstrated experimentally a CuCl electrolyzer in which hydrogen is produced electrolytically at the cathode and Cu(I) is oxidized to Cu(II) at the anode, thereby combining above steps 1 and 4 to ...
4 CuI + Hg → (Cu +) 2 [HgI 4] 2− + 2 Cu. This reaction can be used for the detection of mercury since the white CuI to brown Cu 2 [HgI 4] color change is dramatic. Copper(I) iodide is used in the synthesis of Cu(I) clusters such as [Cu 6 I 7] −. [10] Copper(I) iodide dissolves in acetonitrile, yielding diverse complexes.
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