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[1] [2] [3] A more fundamental statement was later labelled as the zeroth law after the first three laws had been established. The zeroth law of thermodynamics defines thermal equilibrium and forms a basis for the definition of temperature: if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium ...
These are the smallest energy spacings, and their size can be understood by comparing the energy of a diatomic molecule with internuclear spacing ~ 1 Å to the energy of a valence electron (estimated above as ~ ħ/a). [1] Actual molecular spectra also show transitions which simultaneously couple electronic, vibrational, and rotational states.
Laplace's demon is a supreme intelligence who could completely predict the one possible future given the Newtonian dynamical laws of classical physics and perfect knowledge of the positions and velocities of all the particles in the world.
Instead, guidance is set by reference to what is to be taught and learned by the end of Key Stage 3 [the end of year 9 (ages 13/14)] and by the end of Key Stage 4 [the end of year 11 (ages 15/16)]. It is notable that the curriculum for Key Stage 4 is intended by the Department for Education to examine all learning from Key Stages 1 to 4.
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