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Ligands that bind via more than one atom are often termed chelating. A ligand that binds through two sites is classified as bidentate, and three sites as tridentate. The "bite angle" refers to the angle between the two bonds of a bidentate chelate. Chelating ligands are commonly formed by linking donor groups via organic linkers.
Polyfunctional ligands can attach to metals in many ways and thus can bridge metals in diverse ways, including sharing of one atom or using several atoms. Examples of such polyatomic ligands are the oxoanions CO 2− 3 and the related carboxylates, PO 3− 4, and the polyoxometalates.
The interaction of ligands with their binding sites can be characterized in terms of a binding affinity. In general, high-affinity ligand binding results from greater attractive forces between the ligand and its receptor while low-affinity ligand binding involves less attractive force.
The number of ligands coordinating is indicated by the prefixes di-, tri-, tetra- penta- etc. for simple ligands or bis-, tris-, tetrakis-, etc. for complex ligands. For example: [CoCl(NH 3) 5]Cl 2 pentaamminechloridocobalt(3+) chloride where ammine (NH 3)precedes chloride. The central atom name(s) come after the ligands.
Nucleophiles add to odd-hapticity acyclic polyene ligands at a terminal position if the metal is highly electrophilic, otherwise they add at an internal site. Simplified: even before odd and open before closed. The following is a diagram showing the reactivity trends of even/odd hapticity and open/closed π-ligands.
These ligands are sometimes referred to as ancillary ligands. [2] Several different classes of ligand exist that can be considered spectator ligands. A few examples include trispyrazolylborates (Tp), cyclopentadienyl ligands (Cp), and many chelating diphosphines such as 1,2-bis(diphenylphosphino)ethane ligands (dppe). Varying the substituents ...
A ligand binding assay (LBA) is an assay, or an analytic procedure, which relies on the binding of ligand molecules to receptors, antibodies or other macromolecules. [1] A detection method is used to determine the presence and amount of the ligand-receptor complexes formed, and this is usually determined electrochemically or through a fluorescence detection method. [2]
Two tridentate ligands may form a complex with such an atom. There are two possible arrangements for such a complex: fac where the coordination is in a triangle on one face of the octahedron, and mer where the coordinating atoms are in an arc around the central atom, with two atoms of the ligand opposite each other.