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Boron trioxide or diboron trioxide is the oxide of boron with the formula B 2 O 3. It is a colorless transparent solid, almost always glassy (amorphous), which can be crystallized only with great difficulty.
Guitar slide made of borosilicate glass. Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10 −6 K −1 at 20 °C), making them more resistant to thermal shock than any other common glass.
Boron oxide may refer to one of several oxides of boron: Boron trioxide (B 2 O 3, diboron trioxide), the most common form;
The mean oxidation number for the boron atoms is then simply the ratio of hydrogen to boron in the molecule. For example, in diborane B 2 H 6, the boron oxidation state is +3, but in decaborane B 10 H 14, it is 7 / 5 or +1.4. In these compounds the oxidation state of boron is often not a whole number.
Boron carbide – B 4 C [143] Boron nitride – BN [144] Boron suboxide – B 6 O [145] Boron tribromide – BBr 3 [146] Boron trichloride – BCl 3 [147] Boron trifluoride – BF 3 [148] Boron triiodide –BI 3 [149] Boron oxide – B 2 O 3 [150] Boroxine – B 3 H 3 O 3 [151] Decaborane – B 10 H 14 [152] Diborane – B 2 H 6 [153] Diboron ...
At higher temperatures boron burns to form boron trioxide: [51] 4 B + 3 O 2 → 2 B 2 O 3 Ball-and-stick model of tetraborate anion, [B 4 O 5 (OH) 4 ] 2− , as it occurs in crystalline borax, Na 2 [B 4 O 5 (OH) 4 ]·8H 2 O. Boron atoms are pink, with bridging oxygens in red, and four hydroxyl hydrogens in white.
A reaction of Br 2 with O 3 at 273 K and low pressure. [3] [4] [5] Physical properties. The compound forms a white solid. [6] It exists in two forms which are both ...
The first synthesis was done by Poggiale in 1846 by reacting boron trioxide with carbon and bromine at high temperatures: [7] B 2 O 3 + 3 C + 3 Br 2 → 2 BBr 3 + 3 CO. An improvement of this method was developed by F. Wöhler and Deville in 1857. By starting from amorphous boron the reaction temperatures are lower and no carbon monoxide is ...