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Name of straight chain Synonyms 1 1 1 CH 4: methane: methyl hydride; natural gas 2 1 1 C 2 H 6: ethane: dimethyl; ethyl hydride; methyl methane 3 1 1 C 3 H 8: propane: dimethyl methane; propyl hydride 4 2 2 C 4 H 10: n-butane: butyl hydride; methylethyl methane 5 3 3 C 5 H 12: n-pentane: amyl hydride; Skellysolve A 6 5 5 C 6 H 14: n-hexane
The shorter of the two chains becomes the first part of the name with the -ane suffix changed to -oxy, and the longer alkane chain becomes the suffix of the name of the ether. Thus, CH 3 OCH 3 is methoxymethane, and CH 3 OCH 2 CH 3 is methoxyethane (not ethoxymethane). If the oxygen is not attached to the end of the main alkane chain, then the ...
For many common compounds the substituent is linked at one end (the 1 position) and historically not numbered in the name. The IUPAC 2013 Rules [7] however do require an explicit locant for most substituents in a preferred IUPAC name. The substituent name is modified by stripping -ane (see alkane) and adding the
Chemical structure of methane, the simplest alkane. In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. [1]
Combining the names of functional groups with the names of the parent alkanes generates what is termed a systematic nomenclature for naming organic compounds. In traditional nomenclature, the first carbon atom after the carbon that attaches to the functional group is called the alpha carbon ; the second, beta carbon, the third, gamma carbon, etc.
Thus, the name is 3-methylpentane to avoid ambiguity: The 3- is because the methyl is attached to the third of the five carbon atoms. If there is more than one of the same alkyl group attached to a chain, then the prefixes are used on the alkyl groups to indicate multiples (i.e., di, tri, tetra, etc.)
The naming of polycyclic alkanes such as bicyclic alkanes and spiro alkanes is more complex, with the base name indicating the number of carbons in the ring system, a prefix indicating the number of rings ( "bicyclo-" or "spiro-"), and a numeric prefix before that indicating the number of carbons in each part of each ring, exclusive of ...
Naming alkanes per standards listed in the IUPAC Gold Book is done according to the Klyne–Prelog system for specifying angles (called either torsional or dihedral angles) between substituents around a single bond: [25] syn/anti peri/clinal. a torsion angle between 0° and ±90° is called syn (s) a torsion angle between ±90° and 180° is ...