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The first type, shown on the right and left of the diagram, uses an electrolyte of sodium chloride solution, a graphite anode (A), and a mercury cathode (M). The other type of cell, shown in the center of the diagram, uses an electrolyte of sodium hydroxide solution, a mercury anode (M), and an iron cathode (D). The mercury electrode is common ...
The most common chloralkali process involves the electrolysis of aqueous sodium chloride (a brine) in a membrane cell. A membrane, such as Nafion, Flemion or Aciplex, is used to prevent the reaction between the chlorine and hydroxide ions. Basic membrane cell used in the electrolysis of brine.
Chlorine can be manufactured by the electrolysis of a sodium chloride solution (), which is known as the Chloralkali process.The production of chlorine results in the co-products caustic soda (sodium hydroxide, NaOH) and hydrogen gas (H 2).
In the chloralkali process (electrolysis of brine) a water/sodium chloride mixture is only half the electrolysis of water since the chloride ions are oxidized to chlorine rather than water being oxidized to oxygen. Thermodynamically, this would not be expected since the oxidation potential of the chloride ion is less than that of water, but the ...
The water used is usually brackish water or brine (i.e. a solution with >0.5% salinity). In these cases, additional contaminant chemicals may be present in the water feed. The low voltage DC current still performs electrochlorination. The excess chemicals are left untouched and can be easily discarded. [2]
Diagram of Castner process apparatus. The Castner process is a process for manufacturing sodium metal by electrolysis of molten sodium hydroxide at approximately 330 °C. Below that temperature, the melt would solidify; above that temperature, the molten sodium would start to dissolve in the melt.
The Downs cell uses a carbon anode and an iron cathode.The electrolyte is sodium chloride that has been heated to the liquid state. Although solid sodium chloride is a poor conductor of electricity, when molten the sodium and chloride ions are mobilized, which become charge carriers and allow conduction of electric current.
Electrochemical engineering is applied in industrial water electrolysis, electrolysis, electrosynthesis, electroplating, fuel cells, flow batteries, [8] decontamination of industrial effluents, electrorefining, electrowinning, etc. The primary example of an electrolysis-based process is the Chloralkali process for caustic soda and chlorine ...