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Following the UN model, the DOT divides regulated hazardous materials into nine classes, some of which are further subdivided. Hazardous materials in transportation must be placarded and have specified packaging and labelling. Some materials must always be placarded, others may only require placarding in certain circumstances. [23]
The packing group of Division 6.1 materials shall be as assigned in Column 5 of the 49CFR 172.101 Table. When the 49CFR 172.101 Table provides more than one packing group or hazard zone for a hazardous material, the packing group and hazard zone shall be determined by applying the following criteria: 1.
The material is forbidden from being offered for transportation according to 49CFR 172.101 of this subchapter or 49CFR 173.21; The Associate Administrator for Hazardous Materials Safety has determined that the material does not present a hazard which is associated with a Division 5.2 material; or; The material meets one of the following conditions:
n.o.s. = not otherwise specified meaning a collective entry to which substances, mixtures, solutions or articles may be assigned if a) they are not mentioned by name in 3.2 Dangerous Goods List AND b) they exhibit chemical, physical and/or dangerous properties corresponding to the Class, classification code, packing group and the name and description of the n.o.s. entry [4]
It is in the Secretary's authority to designate material or a group or class of material as hazardous when they meet the definition of hazardous material under the Act. A hazardous material , as defined by the Secretary, is any particular quantity or form of a material that may pose an unreasonable risk to health and safety or property during ...
A United States placard showing the UN number 1814, indicating potassium hydroxide solution, on a railroad tank car.. A UN number (United Nations number) is a four-digit number that identifies hazardous materials, and articles (such as explosives, flammable liquids, oxidizers, toxic liquids, etc.) in the framework of international trade and transport.