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Oxalate also forms coordination compounds where it is sometimes abbreviated as ox. It is commonly encountered as a bidentate ligand. When the oxalate chelates to a single metal center, it always adopts the planar conformation. As a bidentate ligand, it forms a 5-membered MC 2 O 2 ring. An illustrative complex is potassium ferrioxalate, K 3 [Fe ...
Potassium hydrogenoxalate is a salt with formula KHC 2 O 4 or K + ·HO 2 C-CO 2 −.It is one of the most common salts of the hydrogenoxalate anion, and can be obtained by reacting potassium hydroxide with oxalic acid in 1:1 mole ratio.
The compound is a salt consisting of ferrioxalate anions, [Fe(C 2 O 4) 3] 3−, and potassium cations K +. The anion is a transition metal oxalate complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate C 2 O 2− 4 ligands. Potassium is a counterion, balancing the −3 charge of the complex.
This page was last edited on 30 July 2010, at 20:37 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may ...
Potassium ferrioxalate crystals. Metal oxalate complexes are photoactive, degrading with loss of carbon dioxide. This reaction is the basis of the technique called actinometry. Ferrioxalate undergoes photoreduction. The iron centre is reduced (gains an electron) from the +3 to the +2 oxidation state, while an oxalate ion is oxidised to carbon ...
potassium oxalate: 583–52–8 K 2 C 4 H 6 O 6: potassium tartrate: 921–53–9 K 2 C 6 H 8 O 4: potassium adipate: 19147–16–1 K 2 CrO 4: potassium chromate: 7789–00–6 K 2 Cr 2 O 7: potassium dichromate: 7778–50–9 K 2 FeO 4: potassium ferrate: 39469–86–8 K 2 S 2 O 3: potassium thiosulfate: 10294–66–3 K 2 O: potassium oxide ...
In addition to the neutral rubidium oxalate Rb 2 C 2 O 4, there is also an acidic salt, rubidium hydrogen oxalate with the formula RbHC 2 O 4, which is isomorphic to potassium hydrogen oxalate KHC 2 O 4 [10] and forms monoclinic crystals, [11] and an acidic dioxalate with the formula RbHC 2 O 4 ·H 2 C 2 O 4, which exists as a dihydrate, has a ...
Ammonium oxalate is a chemical compound with the chemical formula [N H 4] 2 C 2 O 4.Its formula is often written as (NH 4) 2 C 2 O 4 or (COONH 4) 2.It is an ammonium salt of oxalic acid.It consists of ammonium cations ([NH 4] +) and oxalate anions (C 2 O 2− 4).