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[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Being the conjugate base of a strong acid (nitric acid, pK a = -1.4), nitrate has modest Lewis basicity.Two coordination modes are common: unidentate and bidentate.Often, bidentate nitrate, denoted κ 2-NO 3, is bound unsymmetrically in the sense that one M-O distance is clearly bonding and the other is more weakly interacting. [2]
The program can read and write many file formats, other than its proprietary sketch file format (.skc) and can export PNG files. If SVG files are required, it is recommended that structure diagrams be exported as enhanced metafiles (.emf) which can be read by Inkscape and other image editors..
Nitrate is a polyatomic ion with the chemical formula NO − 3. Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. [1] Almost all inorganic nitrates are soluble in water. An example of an insoluble nitrate is bismuth oxynitrate.
The O and O,O-bidentate modes are hard ligands, being found on Lewis-acidic metal centers. The kinetically-favored O-bonded isomer [(NH 3) 5 Co−ONO] 2+ converts to [(NH 3) 5 Co−NO 2] 2+. In its reaction with ferric porphyrin complexes, nitrite gives the O-bonded isomer, Fe(porph)ONO. Addition of donor ligands to this complex induces the ...
For example: H 2 N 2 O 2 + 2 H + + 2 e − ⇌ N 2 + 2 H 2 O; E 0 = +2.65 V. Oxidation reactions usually result in the formation of the nitrate ion, with nitrogen in oxidation state +5. For example, oxidation with permanganate ion can be used for quantitative analysis of nitrite (by titration): 5 NO − 2 + 2 MnO − 4 + 6 H + → 5 NO − 3 ...
A typical reaction with silver nitrate is to suspend a rod of copper in a solution of silver nitrate and leave it for a few hours. The silver nitrate reacts with copper to form hairlike crystals of silver metal and a blue solution of copper nitrate: 2 AgNO 3 + Cu → Cu(NO 3) 2 + 2 Ag. Silver nitrate decomposes when heated:
A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite (NO − 2) and nitrate (NO − 3) anions. They are mixed-anion compounds, and they are mixed-valence compounds. Some have third anions. Many nitrite nitrate compounds are coordination complexes of cobalt.