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The general equation can then be written as [6] = + + (),. where the "force" term corresponds to the forces exerted on the particles by an external influence (not by the particles themselves), the "diff" term represents the diffusion of particles, and "coll" is the collision term – accounting for the forces acting between particles in collisions.
Gas kinetics is a science in the branch of fluid dynamics, concerned with the study of motion of gases and its effects on physical systems. Based on the principles of fluid mechanics and thermodynamics , gas dynamics arises from the studies of gas flows in transonic and supersonic flights .
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The configuration space and the phase space of the dynamical system both are Euclidean spaces, i. e. they are equipped with a Euclidean structure.The Euclidean structure of them is defined so that the kinetic energy of the single multidimensional particle with the unit mass = is equal to the sum of kinetic energies of the three-dimensional particles with the masses , …,:
The derivation of the Navier–Stokes equations as well as their application and formulation for different families of fluids, is an important exercise in fluid dynamics with applications in mechanical engineering, physics, chemistry, heat transfer, and electrical engineering.
The difference between states A and B may be in the atom types involved, in which case the ΔF obtained is for "mutating" one molecule onto another, or it may be a difference of geometry, in which case one obtains a free-energy map along one or more reaction coordinates. This free-energy map is also known as a potential of mean force (PMF).
As an example, consider the gas-phase reaction NO 2 + CO → NO + CO 2.If this reaction occurred in a single step, its reaction rate (r) would be proportional to the rate of collisions between NO 2 and CO molecules: r = k[NO 2][CO], where k is the reaction rate constant, and square brackets indicate a molar concentration.
In the physical science of dynamics, rigid-body dynamics studies the movement of systems of interconnected bodies under the action of external forces.The assumption that the bodies are rigid (i.e. they do not deform under the action of applied forces) simplifies analysis, by reducing the parameters that describe the configuration of the system to the translation and rotation of reference ...