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  2. Cis effect - Wikipedia

    en.wikipedia.org/wiki/Cis_effect

    The system most often studied for the cis effect is an octahedral complex M(CO) 5 X where X is the ligand that will labilize a CO ligand cis to it. Unlike the trans effect, which is most often observed in 4-coordinate square planar complexes, the cis effect is observed in 6-coordinate octahedral transition metal complexes.

  3. Trans effect - Wikipedia

    en.wikipedia.org/wiki/Trans_effect

    The analogous cis effect is most often observed in octahedral transition metal complexes. In addition to this kinetic trans effect, trans ligands also have an influence on the ground state of the molecule, the most notable ones being bond lengths and stability. Some authors prefer the term trans influence to distinguish it from the kinetic ...

  4. Cis–trans isomerism - Wikipedia

    en.wikipedia.org/wiki/Cistrans_isomerism

    Cis and trans isomers occur both in organic molecules and in inorganic coordination complexes. Cis and trans descriptors are not used for cases of conformational isomerism where the two geometric forms easily interconvert, such as most open-chain single-bonded structures; instead, the terms " syn " and " anti " are used.

  5. Octahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Octahedral_molecular_geometry

    For ML a 4 L b 2, two isomers exist.These isomers of ML a 4 L b 2 are cis, if the L b ligands are mutually adjacent, and trans, if the L b groups are situated 180° to each other. It was the analysis of such complexes that led Alfred Werner to the 1913 Nobel Prize–winning postulation of octahedral complexes.

  6. Stereoisomerism - Wikipedia

    en.wikipedia.org/wiki/Stereoisomerism

    Traditionally, double bond stereochemistry was described as either cis (Latin, on this side) or trans (Latin, across), in reference to the relative position of substituents on either side of a double bond. A simple example of cis–trans isomerism is the 1,2-disubstituted ethenes, like the dichloroethene (C 2 H 2 Cl 2) isomers shown below. [7]

  7. Tetradentate ligand - Wikipedia

    en.wikipedia.org/wiki/Tetradentate_ligand

    This arrangement is illustrated by complexes of the Trost ligand. The ligand can bend so that one donor atom is at the pole and the remaining three are on the equator of the central atom. This is called cis-β (beta). The remaining octahedral positions are cis (adjacent) to each other. The triangles of coordinating atoms and the central atom ...

  8. What College Football Playoff games are today? Breaking down ...

    www.aol.com/college-football-playoff-games-today...

    The College Football Playoff got underway Friday but the main course is spread out through Saturday. Three first-round games will be played across three separate campus sites from State College ...

  9. Reductive elimination - Wikipedia

    en.wikipedia.org/wiki/Reductive_elimination

    For a nondissociative pathway, reductive elimination occurs from the four-coordinate system to afford a two-coordinate complex. If the eliminating ligands are trans to each other, the complex must first undergo a trans to cis isomerization before eliminating. In an associative mechanism, a ligand must initially associate with the four ...

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