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The grand canonical partition function applies to a grand canonical ensemble, in which the system can exchange both heat and particles with the environment, at fixed temperature, volume, and chemical potential. Other types of partition functions can be defined for different circumstances; see partition function (mathematics) for
In number theory and combinatorics, a partition of a non-negative integer n, also called an integer partition, is a way of writing n as a sum of positive integers. Two sums that differ only in the order of their summands are considered the same partition. (If order matters, the sum becomes a composition.)
The values (), …, of the partition function (1, 2, 3, 5, 7, 11, 15, and 22) can be determined by counting the Young diagrams for the partitions of the numbers from 1 to 8. In number theory, the partition function p(n) represents the number of possible partitions of a non-negative integer n.
The partition function ties together many different concepts, and thus offers a general framework in which many different kinds of quantities may be calculated. In particular, it shows how to calculate expectation values and Green's functions, forming a bridge to Fredholm theory.
Partitions of a 4-element set ordered by refinement. A partition α of a set X is a refinement of a partition ρ of X—and we say that α is finer than ρ and that ρ is coarser than α—if every element of α is a subset of some element of ρ. Informally, this means that α is a further fragmentation of ρ. In that case, it is written that ...
The partition coefficient between n-Octanol and water is known as the n-octanol-water partition coefficient, or K ow. [62] It is also frequently referred to by the symbol P, especially in the English literature.
The generalized version of the partition function provides the complete framework for working with ensemble averages in thermodynamics, information theory, statistical mechanics and quantum mechanics. The microcanonical ensemble represents an isolated system in which energy (E), volume (V) and the number of particles (N) are all constant.
Density matrices make it much easier to describe the process and calculate its consequences. Quantum decoherence explains why a system interacting with an environment transitions from being a pure state, exhibiting superpositions, to a mixed state, an incoherent combination of classical alternatives.