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Sediment samples to be analyzed are first purged with argon or nitrogen gas to ensure they are anoxic. The sample is placed in a flask connected to an apparatus for trapping hydrogen sulfide gas (H 2 S). Oxygen-free water and hydrochloric acid (HCl) are added, and the sediment is stirred for one hour while argon or nitrogen gas is bubbled ...
A hydrogen sulfide bloom (green) stretching for about 150km along the coast of Namibia. As oxygen-poor water reaches the coast, bacteria in the organic-matter rich sediment produce hydrogen sulfide, which is toxic to fish. Hydrogen sulfide has been implicated in several mass extinctions that have occurred in the
These reactive species can be applied in water and can oxidize virtually any compound present in the water matrix, often at a diffusion-controlled reaction speed. Consequently, ·OH reacts unselectively once formed and contaminants will be quickly and efficiently fragmented and converted into small inorganic molecules.
Various methods exist to treat sulfur in water. These methods include Filtration of the water using a carbon filter (useful for very small amounts of hydrogen sulfide) Filtration of the water through a canister of manganese oxide coated greensand; Aeration of the water; Chlorination of water (can be used to treat large amounts of hydrogen sulfide)
The first in which biological sulfur reduction occurs, the second through which dissolved H 2 S in wastewaters is stripped into hydrogen sulfide gas, and the third consists in the treatment of flue gases, removing over 90% of SO 2 and NO, according to this study. Furthermore, the 88% of the sulfur input would be recovered as octasulfur and then ...
Many gases have toxic properties, which are often assessed using the LC 50 (median lethal concentration) measure. In the United States, many of these gases have been assigned an NFPA 704 health rating of 4 (may be fatal) or 3 (may cause serious or permanent injury), and/or exposure limits (TLV, TWA/PEL, STEL, or REL) determined by the ACGIH professional association.
Elemental bromine (Br 2) is toxic and causes chemical burns on human flesh. Inhaling bromine gas results in similar irritation of the respiratory tract, causing coughing, choking, shortness of breath, and death if inhaled in large enough amounts. Chronic exposure may lead to frequent bronchial infections and a general deterioration of health.
Biogenic sulfide corrosion is a bacterially mediated process of forming hydrogen sulfide gas and the subsequent conversion to sulfuric acid that attacks concrete and steel within wastewater environments. The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid.