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A typical flow battery consists of two tanks of liquids which are pumped past a membrane held between two electrodes. [1]A flow battery, or redox flow battery (after reduction–oxidation), is a type of electrochemical cell where chemical energy is provided by two chemical components dissolved in liquids that are pumped through the system on separate sides of a membrane.
A cathode-flow lithium-iodine (Li–I) battery uses the triiodide/iodide (I3 − /I −) redox couple in aqueous solution.It has energy density of 0.33 kWh/kg because of the solubility of LiI in aqueous solution (≈8.2M) and its power density of 130 mW/cm 2 at a current rate of 60 mA/cm 2, 328 K.
Zinc–bromine flow batteries do not enjoy the advantage of scale that other flow-battery technologies enjoy. Storage capacity cannot be increased by simply adding additional electrolyte tanks (the stack must also be scaled up). Zinc-bromine hybrid-flow batteries have many specific disadvantages:
Under certain conditions, some battery chemistries are at risk of thermal runaway, leading to cell rupture or combustion.As thermal runaway is determined not only by cell chemistry but also cell size, cell design and charge, only the worst-case values are reflected here.
Lithium-ion polymer battery (LiPo) Lithium–iron–phosphate battery (LFP) Lithium–nickel–manganese–cobalt oxides (NMC) Lithium–nickel–cobalt–aluminium oxides (NCA) Lithium–sulfur battery; Lithium–titanate battery (LTO) Thin-film lithium-ion battery; Lithium–ceramic battery [2] [3] Rechargeable lithium–metal battery ...
The UNSW All-Vanadium Redox Flow Battery patents and technology were licensed to Mitsubishi Chemical Corporation and Kashima-Kita Electric Power Corporation in the mid-1990s and subsequently acquired by Sumitomo Electric Industries where extensive field testing was conducted in a wide range of applications in the late 1990s and early 2000s. [20]