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The spectral series of hydrogen, on a logarithmic scale. The emission spectrum of atomic hydrogen has been divided into a number of spectral series, with wavelengths given by the Rydberg formula. These observed spectral lines are due to the electron making transitions between two energy levels in an atom.
A hydrogen atom with proton and electron spins aligned (top) undergoes a flip of the electron spin, resulting in emission of a photon with a 21 cm wavelength (bottom) The hydrogen line, 21 centimeter line, or H I line [a] is a spectral line that is created by a change in the energy state of solitary, electrically neutral hydrogen atoms.
A demonstration of the 589 nm D 2 (left) and 590 nm D 1 (right) emission sodium D lines using a wick with salt water in a flame. The Fraunhofer C, F, G′, and h lines correspond to the alpha, beta, gamma, and delta lines of the Balmer series of emission lines of the hydrogen atom. The Fraunhofer letters are now rarely used for those lines.
The Balmer series is particularly useful in astronomy because the Balmer lines appear in numerous stellar objects due to the abundance of hydrogen in the universe, and therefore are commonly seen and relatively strong compared to lines from other elements. The first two Balmer lines correspond to the Fraunhofer lines C and F. The spectral ...
The phrase "spectral lines", when not qualified, usually refers to lines having wavelengths in the visible band of the full electromagnetic spectrum. Many spectral lines occur at wavelengths outside this range. At shorter wavelengths, which correspond to higher energies, ultraviolet spectral lines include the Lyman series of hydrogen.
In physics and chemistry, the Lyman series is a hydrogen spectral series of transitions and resulting ultraviolet emission lines of the hydrogen atom as an electron goes from n ≥ 2 to n = 1 (where n is the principal quantum number), the lowest energy level of the electron (groundstate).
The HITRAN spectroscopy database lists more than 37,000 spectral lines for gaseous H 2 16 O, ranging from the microwave region to the visible spectrum. [5] [12] In liquid water the rotational transitions are effectively quenched, but absorption bands are affected by hydrogen bonding.
This fact was historically important in convincing Rutherford of the importance of Bohr's model, for it explained the fact that the frequencies of lines in the spectra for singly ionized helium do not differ from those of hydrogen by a factor of exactly 4, but rather by 4 times the ratio of the reduced mass for the hydrogen vs. the helium ...