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A state function describes equilibrium states of a system, thus also describing the type of system. A state variable is typically a state function so the determination of other state variable values at an equilibrium state also determines the value of the state variable as the state function at that state. The ideal gas law is a good example ...
Thermodynamic temperature is a specifically thermodynamic concept, while the original directly measureable state variables are defined by ordinary physical measurements, without reference to thermodynamic concepts; for this reason, it is helpful to regard thermodynamic temperature as a state function.
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More generally, condensation refers to the appearance of macroscopic occupation of one or several states: for example, in BCS theory, a superconductor is a condensate of Cooper pairs. [1] As such, condensation can be associated with phase transition, and the macroscopic occupation of the state is the order parameter.
The concepts of Hess's law can be expanded to include changes in entropy and in Gibbs free energy, since these are also state functions. The Bordwell thermodynamic cycle is an example of such an extension that takes advantage of easily measured equilibria and redox potentials to determine experimentally inaccessible Gibbs free energy values.
An example of an equation of state correlates densities of gases and liquids to temperatures and pressures, known as the ideal gas law, which is roughly accurate for weakly polar gases at low pressures and moderate temperatures. This equation becomes increasingly inaccurate at higher pressures and lower temperatures, and fails to predict ...
One of the simplest examples of such a system is the case of a bathtub with the tap open but without the bottom plug: [dubious – discuss] after a certain time the water flows in and out at the same rate, so the water level (the state variable being Volume) stabilizes and the system is at steady state. Of course the Volume stabilizing inside ...
The steady state approximation, [1] occasionally called the stationary-state approximation or Bodenstein's quasi-steady state approximation, involves setting the rate of change of a reaction intermediate in a reaction mechanism equal to zero so that the kinetic equations can be simplified by setting the rate of formation of the intermediate equal to the rate of its destruction.