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The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
Depiction of a hydrogen atom showing the diameter as about twice the Bohr model radius. (Image not to scale) A hydrogen atom is an atom of the chemical element hydrogen.The electrically neutral hydrogen atom contains a single positively charged proton in the nucleus, and a single negatively charged electron bound to the nucleus by the Coulomb force.
The theory would have correctly explained the Zeeman effect, except for the issue of electron spin. Sommerfeld's model was much closer to the modern quantum mechanical picture than Bohr's. In the 1950s Joseph Keller updated Bohr–Sommerfeld quantization using Einstein's interpretation of 1917, [6] now known as Einstein–Brillouin–Keller method.
But for Bohr the important result was the use of classical analogies and the Bohr atomic model to fix inconsistencies in Planck's derivation of the blackbody radiation formula. [9]: 118 Bohr used the word "correspondence" in italics in lectures and writing before calling it a correspondence principle. He viewed this as a correspondence between ...
Bohr, meanwhile, defended the idea that quantum systems can only have their own reality defined after the scientist has set up the experimental design. “God does not play dice,” Einstein said.
Bohr considered one of the foundational truths of quantum mechanics to be the fact that setting up an experiment to measure one quantity of a pair, for instance the position of an electron, excludes the possibility of measuring the other, yet understanding both experiments is necessary to characterize the object under study. In Bohr's view, the ...
According to Bohr's complementarity principle, light is neither a wave nor a stream of particles. A particular experiment can demonstrate particle behavior (passing through a definite slit) or wave behavior (interference), but not both at the same time. [72] The same experiment has been performed for light, electrons, atoms, and molecules.
The Bohr model of the chemical bond could not explain the properties of the molecules. Attempts to improve it have been undertaken many times, but have not led to success. [3] A working theory of chemical bonding was formulated only by quantum mechanics on the basis of the principle of uncertainty and the Pauli exclusion principle. In contrast ...